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Dipole-driven interlude of mesomorphism in polyelectrolyte solutions---Long ignored, dipole-dipole interactions give life its shape
Dipoles can upend what we know about how charged macromolecules self-assemble. This finding upends our understanding of how some of life’s basic structures are built.
Pd-Catalyzed Asymmetric Allylic Pyridinylation Reaction under Electrochemical Conditions
By combining electricity and Pd catalysis, the first example of an asymmetric allylic pyrdinylation reaction was reported with 4-CN-pyridne as the pyridine source. The Pd catalyst acts not only as the transition-metal catalyst but also as an electron-transfer catalyst.
