The "forbidden" alkene regioisomer during The Mizoroki–Heck coupling reaction of acrylates and styrenes, i.e. the alpha coupling product, is now achieved by employing substrate– or zeolite–hindered chemical enviroments with palladium single atom and sub–nanometric cluster catalysts.
The Fletcher group has previously developed a Rh-catalysed asymmetric Suzuki-Miyaura type cross-coupling of racemic halides with arylboronic acids. Here, we explore the mechanism of this highly enantioselective transformation (https://dx.doi.org/10.1038/s41929-021-00589-y).
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